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ZGP ZnGeP2 Zinc Germanium Phosphide Mid IR Nonlinear Large Susceptibility

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Nanjing Crylink Photonics Co.,Ltd
City:shanghai
Province/State:shanghai
Country/Region:china
Contact Person:Mrsales
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ZGP ZnGeP2 Zinc Germanium Phosphide Mid IR Nonlinear Large Susceptibility

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Place of Origin :China
Brand Name :CRYLINK
Certification :Iso9001
MOQ :1 Pieces
Price :negotiation
Packaging Details :Carton
Delivery Time :3-4 weeks
Payment Terms :TT
Supply Ability :100 pieces /month
Model Number :CRYLINK-ZGP(ZnGeP2) Nonlinear Crystal
Name :ZGP(ZnGeP2)
Crystal Structure :Tetragonal,`42m
Lattice Parameter :a=b=5.467, c=12.736
Mass Density :4.16 g/cm3
Moh Hardness :5.5
Melting Point :About 1040°C
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ZnGeP2(Zinc germanium phosphide)crystal has many good properties and is an mid-IR nonlinear crystal. The nonlinear susceptibility of ZnGeP2 (ZGP) crystal is approximately 160 times large (d36~75 pm/V) as KDP,.ZGP shows good optical transparency over the 0.7412 mm and relatively high laser damage threshold, and is therefore well suited for producing near infrared tunable laser. ZGP is a very hopeful material for mid-infrared devices such as SHG, SFG, OPO, and OPG/OPA.

Chemical and Physical properties

Property Value
Chemical Formula ZnGeP2
Crystal Structure Tetragonal,`42m
Lattice Parameter a=b=5.467, c=12.736
Mass Density 4.16 g/cm3
Moh Hardness 5.5
Melting Point About 1040°C
Thermal Conductivity 180 W/m/K
Thermal Expansion Coefficient ‖,5×10-6/K; ⊥,7.8×10-6/K
Birefringence positive uniaxial

Linear Optical Properties
Property Value
Transparency Range 0.74 12 um
Absorption Coefficient <0.05cm-1 @2050-2100 nm
Refractive Indices
@ 2.05 um no = 3.1478, ne = 3.1891
@ 2.79 um no = 3.1333, ne = 3.1744
@ 5.30 um no = 3.1136, ne = 3.1547
@ 10.6 um no = 3.0729, ne = 3.1143
Sellmeier Equations( in m) no2() = 4.64467+5.10087/(2-0.13656)+4.277772/(2-1653.89)
ne2() = 4.71539+5.26358/(2-0.14386)+2.373102/(2-1000.82)

Nonlinear Optical Properties
Property Value
SHG Phase Matchable Range 3177 10357nm (Type I)
NLO coefficients d36=758 pm/V
Typedeeo=d36 sin2cos2
Typedoeo=deoo=d36 sinsin2
Damage Threshold
at 2.79 um 30 GW/cm2 (150 ps)
at 10.6 um 1 GW/cm2 (2 ns)

Linear Absorption Coefficient
[um] [cm-1] Note
1.064 1.52
1.06 best crystals
1.9 0.80.95
2 0.15 o-wave, best crystals
0.16
2.05 0.35
0.26 o-wave
0.23
0.2 o-wave, after annealing
<0.1 best crystals
0.09 best crystals
0.020.04 after annealing and radiation processing
2.08 0.62 o-wave, mean value
1.2 e-wave, mean value
2.15 0.6
0.090.25 typical crystals, o-wave
0.03 best crystals, o-wave
2.39 0.55
2.5 0.11 o-wave, as-grown crystals
2.58 <0.1
2.58.3 <0.2
2.58.5 <0.1
2.73 0.03
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